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Review J. Braz. Chem. Soc. 2024

Prenylated and Geranylated Derivatives of Non-Oxidized Monomeric Acylphloroglucinols of Natural Origin: Occurrence, Biological Properties and Spectroscopic Data

Tainá M. Arrospide; Lucas H. N. Sousa; Marcela C. N. Diniz; Fabrício G. Menezes; Renata M. Araújo

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Spectroscopic, chemical and biological data published between 1965-2022 on acylphloroglucinol derivatives are compiled in this review.

https://dx.doi.org/10.21577/0103-5053.20240021

Published online: February 15, 2024

 

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Review J. Braz. Chem. Soc. 2024, 35(3), 1-14

Occurrence of Antibiotics in Aqueous Matrices: An Outlook about the Situation in Brazil

Karla V. L. Lima; Jany H. F. de Jesus; Raquel F. P. Nogueira

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The occurrence of antibiotics in the Brazilian aqueous matrix was carefully revised. The publication of 24 articles on this occurrence revealed the detection of 23 antibiotics in 5 aquatic matrices, ranging from 0.13 to 37300 ng L−1.

https://dx.doi.org/10.21577/0103-5053.20230196

Published online: December 6, 2023

 

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Review J. Braz. Chem. Soc. 2024, 35(1), 1-16

The World of Cave Microbiomes: Biodiversity, Ecological Interactions, Chemistry, and the Multi-Omics Integration

Natália N. Kato; Gabriel S. Arini; Ricardo Roberto Silva; Maria Elina Bichuette; José Augusto P. Bitencourt; Norberto P. Lopes

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The cave ecosystem hosts a high diversity of microorganisms with complex strategies to survive in limited environmental conditions. Here, we highlight the biology and chemistry of cave microbiomes with multi-omics perspectives.

https://dx.doi.org/10.21577/0103-5053.20230148

Published online: September 1, 2023

 

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Review J. Braz. Chem. Soc. 2024, 35(1), 1-18

Biochar and Hydrochar in the Development and Application of Electrochemical Devices in the Sensing and Degradation of Target Compounds: A Mini-Review of the Recent Contributions of 2020-2023

Jonatas O. S. Silva ; Honnara S. Granja ; José F. dos Santos ; Lisiane S. Freitas ; Eliana M. Sussuchi

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We discuss the use of biochars and hydrochars in electrodes applied in the electrochemical sensing and degradation of target compounds.

https://dx.doi.org/10.21577/0103-5053.20230143

Published online: August 22, 2023

 

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Review J. Braz. Chem. Soc. 2024, 35(1), 1-32

Advances in Breast Cancer Drug Discovery: A Review of Therapeutic Strategies and Studies Involving Photosensitizers, Caged Xanthones and Thiosemicarbazones Derivatives

Douglas D. S. Oliveira; Thibault J. W. Jacques Dit Lapierre ; Fernanda C. Silva; Ieda V. Cunha; Rafael A. C. Souza;
Patrícia A. Matos ; Gustavo M. Almeida; Carolina G. Oliveira ; Thaise G. Araújo; Tayana M. Tsubone ; Celso O. Rezende Jr.

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This review presents the principal aspects of the drug discovery process targeting breast cancer and highlights the most promising derivatives of caged xanthones and thiosemicarbazones explored in conventional therapy. Also, it presents details of photodynamic therapy and the action of photosensitizers as an alternative therapy for breast cancer.

https://dx.doi.org/10.21577/0103-5053.20230128

Published online: August 4, 2023

 

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Account J. Braz. Chem. Soc. 2024, 35(1), 1-18

The Art of Scientific Writing and Ethical Use of Artificial Intelligence

Brenno Amaro D. Neto ; Marcos N. Eberlin

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Scientific writing from first words to publication, as well as its challenges, including ethical aspects, are presented and discussed in this opinion manuscript.

https://dx.doi.org/10.21577/0103-5053.20230121

Published online: July 26, 2023

 

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Review J. Braz. Chem. Soc. 2023, 34(11), 1565-1580

The Versatility of Two-Dimensional Liquid Chromatography

Carmen L. Cardoso ; Marcela C. de Moraes ; Quezia B. Cass

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Two-dimensional liquid chromatography (2D-LC) for multiple applications.

https://dx.doi.org/10.21577/0103-5053.20230118

Published online: July 20, 2023

 

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Review J. Braz. Chem. Soc. 2023, 34(11), 1542-1564

Capillary Electromigration Techniques Applied to Clinical Chemistry Investigations and Alternative Diagnostic Assays: Possibilities and Perspectives

Olívia B. O. Moreira ; Bruna M. Berlande; Jéssica C. Q. de Souza ; João Marcos B. Candido ; Lauren H. Jaeger ;
Luiz Henrique C. Adriano; Marco Antônio D. A. e Brito; Maria Patrícia do Nascimento ; Patrícia A. Geraldo; Paula R. Chellini ;
Marcone Augusto L. de Oliveira

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Medicine has been improving the assessment of health-related biomarkers towards precise diagnosis. In this context, we discuss how capillary electromigration techniques stand out as an alternative for the development of new high-efficient cost-effective diagnostic assays.

https://dx.doi.org/10.21577/0103-5053.20230096

Published online: June 13, 2023

 

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Review J. Braz. Chem. Soc. 2023, 34(8), 1041-1070

Recent Synthetic Developments of Asymmetric Multicomponent Transformations: Strecker, Mannich, Passerini and Ugi Reactions

Marcelo H. R. Carvalho; Giovanni W. Amarante ; Pedro P. de Castro

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A general overview on synthetic developments on stereoselective methodologies for Strecker, Mannich, Passerini and Ugi reactions are hereby presented.

https://dx.doi.org/10.21577/0103-5053.20230082

Published online: May 25, 2023

 

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Review J. Braz. Chem. Soc. 2023, 34(7), 897-905

Biogenic Silver Nanoparticles Capped with Proteins: Timed Knowledge and Perspectives

Nelson Durán ; Wagner J. Fávaro ; Silvana Alborés ; Thyerre S. da Costa ; Ljubica Tasic

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Biogenic silver nanoparticles are synthesized through silver(I) reduction promoted by biomolecules. The one-pot biosynthetic process leads to stable silver nanoparticle (AgNP) colloids with surfaces capped by some of the biomolecules that also took part in their synthesis.

https://dx.doi.org/10.21577/0103-5053.20230062

Published online: April 28, 2023

 

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Review J. Braz. Chem. Soc. 2023, 34(6), 755-777

Computation-Guided Support to Experiments by the Exploration of Reaction Mechanisms: Organic Synthesis, Natural Products and Environmental Issues

Karine N. de Andrade ; José Renato D. Fajardo ; Caio A. Leal ; José Walkimar M. Carneiro ; Rodolfo G. Fiorot

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Computational chemistry is a valuable tool for understanding reaction mechanisms and supporting experiments in several areas, such as organic synthesis, natural products (and biochemical transformations), and systems of environmental interest.

https://dx.doi.org/10.21577/0103-5053.20230043

Published online: March 27, 2023

 

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Review J. Braz. Chem. Soc. 2023, 34(5), 615-640

Combining Fluorescent Quantum Dots with Molecularly Imprinted Polymers for the Screening of both Emerging and Classical Environmental Pollutants: A Review

Shakeel Zeb; Javier E. L. Villa; Ademar Wong; Sabir Khan ; Sajjad Hussain; Maria D. P. T. Sotomayor

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Graphically representation of quantum dots (QDs) coated molecular imprinted polymer sensor for the determination of emerging and classical pollutants. Nanoscale QD materials are suitable for fluorescence analysis. The modification with quantum dots provides many advantages such as rapid detection, highly selective and easily operational.

https://dx.doi.org/10.21577/0103-5053.20230015

Published online: January 25, 2023

 

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Review J. Braz. Chem. Soc. 2023, 34(4), 485-501

Marine Natural Products in the Battle against Dengue, Zika, and Chikungunya Arboviruses

Thayssa S. F. Fagundes ; Thatyana R. A. Vasconcelos ; Fernando M. dos Santos Junior ; Bia F. Rajsfus ; Diego Allonso ; José C. J. M. D. S. Menezes ; Alessandra L. Valverde ; Vinicius R. Campos

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The review highlights the different studies on marine natural products with antiviral and larvicidal activity against Dengue, Zika and Chikungunya and their main vector Aedes aegypti.

https://dx.doi.org/10.21577/0103-5053.20230012

Published online: January 20, 2023

 

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Review J. Braz. Chem. Soc. 2023, 34(4), 471-484

Strategies for Metabolomic Analysis of Damaged Skin from Cell and Tissue Samples Using Gas Chromatography-Mass Spectrometry

Samantha C. H. Rodrigues; Helvécio C. Menezes; Dawidson A. Gomes; Zenilda L. Cardeal

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Workflow of gas chromatography coupled to mass spectrometry-based metabolomics analysis of damage skin.

https://dx.doi.org/10.21577/0103-5053.20230005

Published online: January 6, 2023

 

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Review J. Braz. Chem. Soc. 2023, 34(2), 153-166

Fusel Oil: Chemical Composition and an Overview of Its Potential Application

Thainara B. Massa ; Djéssica T. Raspe ; Mirian C. Feiten ; Lúcio Cardozo-Filho ; Camila da Silva

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The production, chemical composition and potential applications of fusel oil were demonstrated.

https://dx.doi.org/10.21577/0103-5053.20220145

Published online: November 22, 2022

 

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Review J. Braz. Chem. Soc. 2022, 33(12), 1353-1374

Reaching Circular Economy through Circular Chemistry: The Basis for Sustainable Development

Lilian L. N. Guarieiro; Michelle J. C. Rezende; Willams T. Barbosa; Gisele O. da Rocha; Pedro Afonso P. Pereira; Daniella R. Fernandes; Wilson A. Lopes; Claudio J. A. Mota ; Jailson B. de Andrade

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The circular economy and circular chemistry play an important role in the challenges and issues related to sustainability.

https://dx.doi.org/10.21577/0103-5053.20220119

Published online: September 12, 2022

 

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Review J. Braz. Chem. Soc. 2022, 33(8), 870-893

Biosurfactants: Sustainable and Versatile Molecules

Fernanda G. Barbosa; Daylin R. Ribeaux; Thiago Rocha ; Rogger A. M. Costa; Ramiro R. Guzmán; Paulo R. F. Marcelino ; Talita M. Lacerda; Silvio S. da Silva

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Biosurfactants are molecules of animal, vegetable and microbial origin with various industrial applications. Animal and plant biosurfactants are obtained by extractive methods. Microbial biosurfactants are extracelular metabolites and can be obtained by fermentation processes in the biorefineries contexts.

https://dx.doi.org/10.21577/0103-5053.20220074

Published online: May 17, 2022

 

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Review J. Braz. Chem. Soc. 2022, 33(8), 844-869

Technological Perspectives and Economic Aspects of Green Hydrogen in the Energetic Transition: Challenges for Chemistry

Lilian L. N. Guarieiro; Jeancarlo P. dos Anjos; Luciana A. da Silva ; Alex Á. B. Santos; Ewerton E. S. Calixto; Fernando L. P. Pessoa; Jose L. G. de Almeida; Miguel Andrade Filho; Flavio S. Marinho ; Gisele O. da Rocha; Jailson B. de Andrade

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Green is the color of the future.

https://dx.doi.org/10.21577/0103-5053.20220052

Published online: March 24, 2022

 

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Review J. Braz. Chem. Soc. 2022, 33(7), 681-692

Internet of Things as a Tool for Sustainable Analytical Chemistry: A Review

Alegre N. S. Cadeado; Caio C. S. Machado; Geandre C. Oliveira ; Daniela A. S e Silva; Rodrigo A. A. Muñoz ; Sidnei G. Silva

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Internet of things (IoT) can play key role to attend the sustainable development goals. The association of IoT with analytical chemistry enables the real-time analytes monitoring, that assess impacts of human activities on environmental and human health.

https://dx.doi.org/10.21577/0103-5053.20220048

Published online: March 17, 2022

 

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Review J. Braz. Chem. Soc. 2022, 33(6), 509-522

NMR Relaxometry Applied to Chemical Studies of Paramagnetic Metal Cation Complexes: Fundamentals and Applications

Flávio V. C. Kock ; Luiz A. Colnago

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This review provides basic theory of time domain nuclear magnetic resonance (TD-NMR) relaxometry of paramagnetic cations in solution and important applications in electrochemistry, analytical and inorganic chemistry.

https://dx.doi.org/10.21577/0103-5053.20220045

Published online: March 11, 2022

 

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Review J. Braz. Chem. Soc. 2022, 33(7), 664-680

Sustainable Synthetic Strategies for the Preparation of Low Molecular Weight Drugs by Biotech Routes

Patricia G. Ferreira ; Alcione S. de Carvalho ; Wilson C. Santos ; Luana S. M. Forezi ; Fernando C. da Silva ;
Vitor F. Ferreira

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This review intends to show how the challenges for the production of some low molecular weight drugs produced by synthetic routes that involve at least one biotechnological step using microorganisms or enzymes were faced.

https://dx.doi.org/10.21577/0103-5053.20220044

Published online: March 10, 2022

 

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Review J. Braz. Chem. Soc. 2022, 33(8), 824-843

Is Hydrogen Indispensable for a Sustainable World? A Review of H2 Applications and Perspectives for the Next Year

Theodora W. Von Zuben; Daniel E. B. Moreira; Rafael L. Germscheidt; Rafael G. Yoshimura ; Daniel S. Dorretto; Ana B. S. de Araujo; Airton G. Salles Jr. ; Juliano A. Bonacin

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In this review, we present an overview of the uses of hydrogen and its importance to a sustainable society.

https://dx.doi.org/10.21577/0103-5053.20220026

Published online: February 3, 2022

 

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Review J. Braz. Chem. Soc. 2022, 33(7), 637-663

Recent Developments on Palladium-Catalyzed Carbonylation Reactions in Renewable Solvents

Danilo Y. de Albuquerque; Wystan K. O. Teixeira; Senthil Narayanaperumal; Ricardo S. Schwab

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The solvents derived from renewable raw materials can be used as an alternative green media for palladium-catalyzed carbonylation reactions, offering a promising and alternative way to construct a wide array of organic molecules carrying a carbon-oxygen double bond.

https://dx.doi.org/10.21577/0103-5053.20220024

Published online: February 2, 2022

 

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Review J. Braz. Chem. Soc. 2022, 33(7), 610-636

Sustainable and Reusable Sulfonic Acid-Functionalized Task-Specific Ionic Liquid Catalysts for Multicomponent Reactions. A Review

Nicolas S. dos Anjos ; Luiz S. Longo Jr.

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In this review contribution we discuss the use of sulfonic acid-functionalized task-specific ionic liquids as sustainable and reusable catalysts for multicomponent reactions applied to the synthesis of heterocycles and related compounds.

https://dx.doi.org/10.21577/0103-5053.20220021

Published online: January 28, 2022

 

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Review J. Braz. Chem. Soc. 2022, 33(4), 303-326

Microplastics in Latin America Ecosystems: A Critical Review of the Current Stage and Research Needs

Andreia N. Fernandes ; Crislaine Bertoldi; Larissa Z. Lara; Jéssica Stival; Nortom M. Alves; Pedro M. Cabrera; Marco T. Grassi

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A systematic review analyzing 196 studies from 16 territorials in Latin America with information about the current state of knowledge regarding the abundance, distribution, and associated impact of microplastics in different matrices was performed.

https://dx.doi.org/10.21577/0103-5053.20220018

Published online: January 26, 2022

 

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Review J. Braz. Chem. Soc. 2022, 33(8), 815-823

Amino Acid-Based Deep Eutectic Solvents in Biomass Processing - Recent Advances

Gustavo R. Gomes ; Renan R. Mattioli ; Julio Cezar Pastre

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Amino acid-based deep eutectic solvents (DES) as a greener methodology for biomass fractionation and sugars chemical conversion to high value-added compounds.

https://dx.doi.org/10.21577/0103-5053.20210150

Published online: November 10, 2021

 

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Review J. Braz. Chem. Soc. 2022, 33(2), 111-127

Seleno- and Telluro-Functionalization of Quinones: Molecules with Relevant Biological Application

Pâmella S. Cordeiro ; Ingrid C. Chipoline ; Ruan C. B. Ribeiro ; David R. Pinho; Vitor F. Ferreira ; Fernando C. da Silva ; Luana S. M. Forezi ; Vanessa Nascimento

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In this review, the methods for the production of selenium-quinones and tellurium-quinones and their biological applications until 2021 are highlighted.

https://dx.doi.org/10.21577/0103-5053.20210148

Published online: November 3, 2021

 

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Review J. Braz. Chem. Soc. 2021, 32(10), 1895-1911

Iron Ore Tailings: Characterization and Applications

Ottávio R. Carmignano; Sara S. Vieira ; Ana Paula C. Teixeira; Fernando S. Lameiras; Paulo Roberto G. Brandão; Rochel M. Lago

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Iron ore tailings (IOT) are mainly composed of iron oxides, silica, and other minerals such as kaolinite. The IOT can be used for different applications related to the civil construction and a variety of technological applications.

https://dx.doi.org/10.21577/0103-5053.20210100

Published online: July 14, 2021

 

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Review J. Braz. Chem. Soc. 2021, 32(9), 1711-1738

Interfacial Electron Transfer in Dye-Sensitized TiO2 Devices for Solar Energy Conversion

Andressa V. Müller ; Wendel M. Wierzba; Mariana N. Pastorelli; André S. Polo

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The interfacial electron transfer reactions that take place in dye-sensitized TiO2 molecular devices for solar energy conversion govern their efficiency. This review visits general aspects of these reactions.

https://dx.doi.org/10.21577/0103-5053.20210083

Published online: June 8, 2021

 

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Review J. Braz. Chem. Soc. 2021, 32(9), 1687-1710

Nanobiosensors for Pathogenic Agents Detection

Mayra Beltrán-Pineda; Diana Peña-Solórzano ; César Augusto Sierra

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This review provides an overview and update regarding the use of some nanomaterials as biosensors, which have shown attractive results over the last few years.

https://dx.doi.org/10.21577/0103-5053.20210081

Published online: June 1, 2021

 

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Review J. Braz. Chem. Soc. 2021, 32(8), 1499-1518

Absolute Configuration Reassignment of Natural Products: An Overview of the Last Decade

Andrea N. L. Batista ; Bianca R. P. Angrisani; Maria Emanuelle D. Lima; Stephanie M. P. da Silva; Vitória H. Schettini ; Higor A. Chagas; Fernando M. dos Santos Jr.; João M. Batista Jr. ; Alessandra L. Valverde

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This review highlights the increase in the number of absolute configuration reassignments of natural products over the last decade and describes the main approaches used both in the original incorrect assignments and stereochemical corrections. It also provides the readers with critical information for the choice of appropriate methods for unambiguous stereochemical determination.

https://dx.doi.org/10.21577/0103-5053.20210079

Published online: May 27, 2021

 

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Review J. Braz. Chem. Soc. 2021, 32(7), 1301-1344

Biodiesel: An Overview II

Michelle J. C. Rezende ; Ana Lúcia de Lima; Bárbara V. Silva; Claudio J. A. Mota; Ednildo A. Torres; Gisele O. da Rocha; Ingrid M. M. Cardozo; Kênia P. Costa; Lilian L. N. Guarieiro; Pedro A. P. Pereira ; Sabrina Martinez; Jailson B. de Andrade

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Worldwide use and advances in biodiesel research over the past 15 years are reported in this review.

https://dx.doi.org/10.21577/0103-5053.20210046

Published online: April 8, 2021

 

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Review J. Braz. Chem. Soc. 2021, 32(5), 917-952

A Catalysis Guide Focusing on C-H Activation Processes

Renato L. Carvalho; Gleiston G. Dias; Cynthia L. M. Pereira; Pintu Ghosh; Debabrata Maiti ; Eufrânio N. da Silva Júnior

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A C-H activation process represents one of the most advanced tool in the field of organic synthesis nowadays, and it requires knowledge that should be studied and learned. Therefore, carrying out a C-H activation reaction in the right direction, following the right steps, can improve its performance and guarantee plausible results.

https://dx.doi.org/10.21577/0103-5053.20210025

Published online: February 19, 2021

 

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Review J. Braz. Chem. Soc. 2020, 31(12), 2439-2451

Calibration Strategies Applied to Laser-Induced Breakdown Spectroscopy: A Critical Review of Advances and Challenges

Vinicius C. Costa; Diego V. Babos; Jeyne P. Castro; Daniel F. Andrade; Raimundo R. Gamela; Raquel C. Machado ; Marco A. Sperança; Alisson S. Araújo; José A. Garcia; Edenir R. Pereira-Filho

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Several calibration strategies have been reported in the literature over the last few years to improve quantitative analysis using laser-induced breakdown spectroscopy (LIBS).

https://dx.doi.org/10.21577/0103-5053.20200175

Published online: August 28, 2020

 

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Review J. Braz. Chem. Soc. 2020, 31(11), 2176-2199

Supramolecular Approach in Energy Conversion Devices

Ronaldo C. Amaral ; Kassio P. S. Zanoni ; Lais S. Matos ; Neyde Y. Murakami Iha

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This review manly focusses on development of energy conversion devices, such as dye-sensitized solar cells, solar fuels, photosensors and light-emitting devices by outlining investigations carried out at the Laboratory of Photochemistry and Energy Conversion (LFCE) in the University of São Paulo, including researches that led to technological innovation.

https://dx.doi.org/10.21577/0103-5053.20200095

Published online: May 20, 2020

 

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Review J. Braz. Chem. Soc. 2020, 31(2), 230-243

Recent Developments on the Elucidation of Colloidal Aspects of Asphaltenes and Their Relevance to Oilfield Problems

Lia B. S. Balestrin ; Watson Loh

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This review discusses colloidal aspects of crude oil asphaltenes and their impact on oil production issues.

https://dx.doi.org/10.21577/0103-5053.20190257

Published online: November 8, 2019

 

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Review J. Braz. Chem. Soc. 2020, 31(2), 211-229

An Overview of the Photocatalytic H2 Evolution by Semiconductor-Based Materials for Nonspecialists

Ivo F. Teixeira ; Jhon Quiroz; Mauricio S. Homsi; Pedro H. C. Camargo

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We review semiconductor photocatalysts for the H2 evolution reaction that have displayed the best reported activities and quantum efficiencies.

https://dx.doi.org/10.21577/0103-5053.20190255

Published online: November 7, 2019

 

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Review J. Braz. Chem. Soc. 2020, 31(1), 2-14

Serpentinites: Mineral Structure, Properties and Technological Applications

Ottavio Raul D. R. Carmignano; Sara S. Vieira; Paulo Roberto G. Brandao; Alexandre C. Bertoli; Rochel M. Lago

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The serpentine is a versatile mineral family rich in Mg silicate with several polymorphic phases with unique physicochemical properties and potential applications.

https://dx.doi.org/10.21577/0103-5053.20190215

Published online: September 4, 2019

 

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Review J. Braz. Chem. Soc. 2019, 30(12), 2536-2560

(Bio)conjugation Strategies Applied to Fluorescent Semiconductor Quantum Dots

Goreti Pereira; Camila A. P. Monteiro; Gabriela M. Albuquerque; Maria I. A. Pereira; Mariana P. Cabrera; Paulo E. Cabral Filho; Giovannia A. L. Pereira; Adriana Fontes; Beate S. Santos

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In this review we present the state of the art of (bio)conjugation strategies applied to semiconductor quantum dots for biomedical / bioanalytical purposes.

https://dx.doi.org/10.21577/0103-5053.20190163

Published online: July 16, 2019

 

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Review J. Braz. Chem. Soc. 2019, 30(12), 2501-2535

The Research on Porphyrins and Analogues in Brazil: A Small Review Covering Catalytic and other Applications since the Beginning at Universidade de Sao Paulo in Ribeirao Preto until the Joint Venture between Brazilian Researchers and Colleagues from Universidade de Aveiro, Portugal

Shirley Nakagaki ; Kelly A. D. F. Castro; Maria da Graça P. M. S. Neves; Maria do Amparo Faustino; Yassuko Iamamoto

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The aim of this review is to provide insight into porphyrin chemistry research in Brazilian institutions, especially that involving catalytic purposes, and discuss some advances achieved in the topic with the collaboration of researchers from the Universidade de Aveiro, Portugal.

https://dx.doi.org/10.21577/0103-5053.20190153

Published online: July 4, 2019

 

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Review J. Braz. Chem. Soc. 2019, 30(11), 2259-2290

Vibrational Spectroscopy and Chemometrics in Forensic Chemistry: Critical Review, Current Trends and Challenges

Carolina S. Silva; André Braz; Maria Fernanda Pimentel

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The symbiotic relation between vibrational spectroscopy and chemometrics in forensic chemistry contexts.

https://dx.doi.org/10.21577/0103-5053.20190140

Published online: June 18, 2019

 

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Review J. Braz. Chem. Soc. 2019, 30(11), 2243-2258

Raman Imaging Spectroscopy: History, Fundamentals and Current Scenario of the Technique

Hery Mitsutake; Ronei J. Poppi; Márcia C. Breitkreitz

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Representation of a Raman imaging experiment: the spectral array of data and the univariate/multivariate data treatment for the generation of chemical images.

https://dx.doi.org/10.21577/0103-5053.20190116

Published online: May 24, 2019

 

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Review J. Braz. Chem. Soc. 2019, 30(10), 2029-2059

Aspergillus niger: A Hundred Years of Contribution to the Natural Products Chemistry

Mary Anne S. Lima ; Maria da Conceiçao F. de Oliveira; Antônia T. A. Pimenta; Paula K. S. Uchôa

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This review celebrates the centenary of chemical investigations on Aspergillus niger. Structurally diverse secondary metabolites produced by this fungus, besides its potential on selective biotransformation of terpenes, are presented.

https://dx.doi.org/10.21577/0103-5053.20190080

Published online: May 7, 2019

 

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Review J. Braz. Chem. Soc. 2019, 30(10), 2010-2028

Magneto-Responsive Hydrogels: Preparation, Characterization, Biotechnological and Environmental Applications

Emilli C. G. Frachini ; Denise F. S. Petri

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Magneto-responsive hydrogels are important platforms for biomedical applications, such as drug delivery, tissue engineering and cancer therapy, and for environmental applications.

https://dx.doi.org/10.21577/0103-5053.20190074

Published online: April 26, 2019

 

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Review J. Braz. Chem. Soc. 2019, 30(10), 2000-2009

DNA Damage by Endogenous and Exogenous Aldehydes

Marisa H. G. Medeiros

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Formation and biological effects of deoxyribonucleic acid (DNA) adducts from endogenous and exogenous aldehydes.

https://dx.doi.org/10.21577/0103-5053.20190056

Published online: April 9, 2019

 

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Review J. Braz. Chem. Soc. 2019, 30(7), 1341-1349

Films Formed on Carbon Steel in Sweet Environments - A Review

Igor A. Fioravante; Ronaldo S. Nunes; Heloisa A. Acciari; Eduardo N. Codaro

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Illustration of the cross section of an oil pipeline showing the scale formed by sweet corrosion.

https://dx.doi.org/10.21577/0103-5053.20190055

Published online: April 8, 2019

 

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Review J. Braz. Chem. Soc. 2019, 30(6), 1115-1129

Perspectives and Applications of Natural Products as Civilian Defense Devices

Ananda S. Antonio ; Gabriel D. Fonseca; Alvaro J. B. Mendes; Larissa S. M. Wiedemann; Valdir F. Veiga-Junior

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Capsaicin, piperine, gingerol and other pungent natural compounds are technologically developed bioproducts for civilian's self-defense proposes.

https://dx.doi.org/10.21577/0103-5053.20190028

Published online: February 19, 2019

 

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Review J. Braz. Chem. Soc. 2019, 30(4), 717-726

Use of Natural Deep Eutectic Solvents for Polymerization and Polymer Reactions

Analía V. Gómez; Atanu Biswas ; Carmen C. Tadini; Roselayne F. Furtado; Carlucio R. Alves; Huai N. Cheng

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Natural deep eutectic solvents (NADES) comprise a new family of agro-based, eco-friendly reaction media that can replace traditional organic solvents in polymerization and polymer reactions. A review of the current progress in this exciting new field is given in this article.

https://dx.doi.org/10.21577/0103-5053.20190001

Published online: January 8, 2019

 

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Review J. Braz. Chem. Soc. 2019, 30(4), 683-716

RM1 Semiempirical Model: Chemistry, Pharmaceutical Research, Molecular Biology and Materials Science

Nathalia B. D. Lima ; Gerd B. Rocha; Ricardo O. Freire; Alfredo M. Simas

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This review on the RM1 model presents improvements to the methodology as well as a wide range of its applications to theoretical, organic, physical, analytical, and inorganic chemistry, along with their interfaces with medicine, biology, and materials science.

https://dx.doi.org/10.21577/0103-5053.20180239

Published online: December 10, 2018

 

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Account J. Braz. Chem. Soc. 2019, 30(3), 436-453

Synthesis of Bis-Strychnos Alkaloids (-)-Sungucine, (-)-Isosungucine, and (-)-Strychnogucine B from (-)-Strychnine

Senzhi Zhao; Christiana N. Teijaro; Heng Chen; Gopal Sirasani; Shivaiah Vaddypally; Owen O'Sullivan; Michael J. Zdilla; Graham E. Dobereiner ; Rodrigo B. Andrade

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Concise syntheses of bis-Strychnos alkaloids (-)-sungucine, (-)-isosungucine, and (-)-strychnogucine B have been accomplished from (-)-strychnine. Computational chemistry was employed to rationalize the regiochemical course of key transformations therein.

https://dx.doi.org/10.21577/0103-5053.20180217


Account J. Braz. Chem. Soc. 2019, 30(3), 426-435

Using Polymer Reaction Engineering Principles to Help the Environment: The Case of the Canadian Oil Sands Tailings

Joao B. P. Soares ; Fernanda L. Motta

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Typical water-based oil sands extraction process in northern Alberta, Canada and macroscopic schematic for settling tests on mature fine tailings (MFT) after treatment with polymer flocculants.

https://dx.doi.org/10.21577/0103-5053.20180197

Published online: October 3, 2018

 

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Review J. Braz. Chem. Soc. 2018, 29(10), 1999-2025

Deep Eutectic Solvents as Unconventional Media for Multicomponent Reactions

Luiz S. Longo Jr.; Marcus V. Craveiro

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This review article describes the use of deep eutectic solvents (DES) as both solvent and/or catalyst in multicomponent reactions.

https://dx.doi.org/10.21577/0103-5053.20180147

Published online: August 2, 2018

 

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Review J. Braz. Chem. Soc. 2018, 29(10), 1983-1998

Insights into Protein-Ionic Liquid Interactions Aiming at Macromolecule Delivery Systems

Liliam K. Harada; Jorge F. B. Pereira; Welida F. Campos; Erica C. Silva; Carla G. Moutinho; Marta M. D. C. Vila; José M. Oliveira Jr.; José A. Teixeira; Victor M. Balcao; Matthieu Tubino

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Potential for application of ionic liquids in biomimetic drug delivery systems, due to their high compatibility with enzymes and other proteins, promotion of higher selectivities, faster reaction rates and greater enzyme stabilities in biocatalytic reactions, and providing a path for the structural and functional stabilization of protein entities.

https://dx.doi.org/10.21577/0103-5053.20180141

Published online: July 24, 2018

 

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Review J. Braz. Chem. Soc. 2018, 29(5), 1041-1075

Computer-Guided Total Synthesis of Natural Products. Recent Examples and Future Perspectives

Franco Della-Felice; Ronaldo A. Pilli; Ariel M. Sarotti

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The use of nuclear magnetic resonance (NMR) calculations can facilitate the total synthesis of natural products of uncertain structural assignment.

https://dx.doi.org/10.21577/0103-5053.20180027

Published online: February 20, 2018

 

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Review J. Braz. Chem. Soc. 2018, 29(5), 1032-1040

Flow Analysis: Looking Back and Forward

Fábio R. P. Rocha

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Main characteristics and perspectives of the researches on flow analysis.

https://dx.doi.org/10.21577/0103-5053.20180018

Published online: February 6, 2018

 

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Review J. Braz. Chem. Soc. 2018, 29(5), 989-997

Grafting of Quinones on Carbons as Active Electrode Materials in Electrochemical Capacitors

Thierry Brousse; Charles Cougnon; Daniel Bélanger

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Grafting quinone molecules on porous carbons improves their charge storage properties for application as electrode in energy storage systems.

https://dx.doi.org/10.21577/0103-5053.20180015

Published online: February 5, 2018

 

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Review J. Braz. Chem. Soc. 2018, 29(5), 998-1031

Natural Products from Marine Invertebrates and Microorganisms in Brazil between 2004 and 2017: Still the Challenges, More Rewards

Laura P. Ióca; Karen J. Nicacio; Roberto G. S. Berlinck

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Natural products from marine macro- and microorganisms in Brazil encompass a variety of metabolic classes, including complex alkaloids and polyketides, many of which present potent biological activities and have been the subject of synthetic and biosynthetic investigations.

https://dx.doi.org/10.21577/0103-5053.20180016

Published online: February 5, 2018

 

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Review J. Braz. Chem. Soc. 2018, 29(5), 982-988

Development of Web and Mobile Applications for Chemical Toxicity Prediction

Vinicius M. Alves; Rodolpho C. Braga; Eugene Muratov; Carolina H. Andrade

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General workflow for the development and implementation of quantitative structure-activity relationships (QSAR) models in web and mobile applications.

https://dx.doi.org/10.21577/0103-5053.20180013

Published online: January 29, 2018

 

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Review J. Braz. Chem. Soc. 2018, 29(5), 973-981

Nanopharmaceuticals and Their Applications in Bladder Cancer Therapy: a Mini Review

Nelson Durán; Wagner J. Fávaro

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Graphene oxide (GO) and a nanostructured lipid carrier (NLC) carrying doxorubicin (DOX) were effective on in vivo treatment of non-muscle invasive bladder cancer (NMIBC) with an enhancement effect by silencing oncogenes via small interfering RNA (siRNA).

https://dx.doi.org/10.21577/0103-5053.20180011

Published online: January 25, 2018

 

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Review J. Braz. Chem. Soc. 2018, 29(5), 960-972

Fundamental Consideration for Electrochemical Engineering of Supercapattery

Bamidele Akinwolemiwa; George Z. Chen

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Supercapattery is a generic term for a large number of hybrid electrochemical energy storage devices that combine the merits of supercapacitor and rechargeable battery. For engineering design, it is imperative to understand the charge storage mechanisms in the electrodes so that high voltage and space-material efficient stack of multiple cells can be manufactured with optimal performance and commercial affordability.

https://dx.doi.org/10.21577/0103-5053.20180010

Published online: January 23, 2018

 

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Review J. Braz. Chem. Soc. 2018, 29(5), 934-947

Electrochemical Systems for Renewable Energy Conversion from Salinity and Proton Gradients

William G. Morais; Gilberto Lima; Wellington J. A. S. Gomes; Fritz Huguenin

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Working principle and electrode materials of electrochemical systems for energy conversion from proton and salt gradient.

https://dx.doi.org/10.21577/0103-5053.20180008

Published online: January 22, 2018

 

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Review J. Braz. Chem. Soc. 2018, 29(5), 948-959

Green Processing of Strategic Elements Based on Magnetic Nanohydrometallurgy

Ulisses Condomitti; Sabrina N. Almeida; Alceu T. Silveira Jr.; Fernando M. de Melo; Henrique E. Toma

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Separation of strategic elements based on magnetic nanohydrometallurgy.

https://dx.doi.org/10.21577/0103-5053.20180009

Published online: January 22, 2018

 

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Review J. Braz. Chem. Soc. 2018, 29(5), 925-933

Ditryptophan Cross-Links as Novel Products of Protein Oxidation

Verônica Paviani; Gabriel T. Galdino; Janaina N. dos Prazeres; Raphael F. Queiroz; Ohara Augusto

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The formation of ditryptophan cross-links during the oxidation of proteins by biological agents and/or environmental factors is becoming recognized and deserves the attention of more researchers.

https://dx.doi.org/10.21577/0103-5053.20170239

Published online: December 21, 2017

 

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Review J. Braz. Chem. Soc. 2018, 29(5), 916-924

Advances of Submarine Groundwater Discharge Studies in South America

Mariele Paiva; Felipe H. Niencheski

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Submarine groundwater discharge plays an important role on the biogeochemistry of the oceans. How much do we know about this process in South America?

https://dx.doi.org/10.21577/0103-5053.20170220

Published online: December 5, 2017

 

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Account J. Braz. Chem. Soc. 2018, 29(5), 896-915

Determination of Enantioselectivities by Means of Chiral Stationary Phase HPLC in Order to Identify Effective Proline-Derived Organocatalysts

Jorge Vargas-Caporali; Eusebio Juaristi

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Chiral HPLC (high performance liquid chromatography) constitutes a central part in the evaluation of the organocatalytic potential of new ligands in prototypical asymmetric reactions. The graphical abstract correlates in a wordplay a high ee (enantiomeric excess) chromatogram with a good Cat* (catalyst) and a racemic chromatogram with an unsatisfactory Cat*.

https://dx.doi.org/10.21577/0103-5053.20170211

Published online: November 27, 2017

 

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Review J. Braz. Chem. Soc. 2018, 29(3), 435-456

1,2,4- and 1,3,4-Oxadiazoles as Scaffolds in the Development of Antiparasitic Agents

Paulo Pitasse-Santos; Vitor Sueth-Santiago; Marco E. F. Lima

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This review focuses on the importance of 1,2,4- and 1,3,4-oxadiazole cores in the design of new antiparasitic drugs. Here are highlighted the synthetic methodologies for their preparation as well as physicochemical differences between the isomers and their binding properties with biological receptors.

https://dx.doi.org/10.21577/0103-5053.20170208

Published online: November 23, 2017

 

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Online version ISSN 1678-4790 Printed version ISSN 0103-5053
Journal of the Brazilian Chemical Society
JBCS Editorial and Publishing Office
University of Campinas - UNICAMP
13083-970 Campinas-SP, Brazil

Free access

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