Novel Bioactive Compounds
from Plants

Over the last few years there has been a resurgence of interest in the investigation of organisms of terrestrial and marine origin for the identification of novel active chemotypes as leads for drug development. 1-3 For example, of 87 approved anticancer drugs available in 1994, 62% were either of natural origin or were modeled on natural product lead compounds. 1 Therefore, as a result of the excellent track record of natural product investigations in affording new drugs, coupled with the loss of biodiversity presently occurring in ecosystems all over the world, it has been argued that natural product drug discovery research should intensify rather than diminish or remain static in the coming years. 1
Recent collaborative work phytochemical performed in the author's laboratory has been aimed at three types of biologically active compounds from higher plants, with potential utility as cancer chemotherapeutic agents,4 cancer chemopreventives,5 and dietary sucrose substitutes, 6 respectively. Efforts directed towards the discovery of anticancer agents have occurred within the framework of a National Cooperative Natural Product Drug Discovery Groups project, funded by the U.S. National Cancer Institute, and involving the participation of a university, a private research institute, and a pharmaceutical company. 4 The work on cancer chemoprevention is another large research program, having individual projects on plant collection, phytochemistry, in vitro biology, and synthetic chemistry. 5 The research to find new sweet substances has been of a smaller scale, but has emphasized field observations on candidate sweet-tasting plants. 6 Structurally characterized bioactive isolates afforded in these programs have included substances in the alkaloid, flavonoid, lignan, proanthocyanidin, stilbenoid, and terpenoid classes of plant secondary metabolites. 4-6

Acknowledgment. The author gratefully acknowledges funding from NIH grants CA48112 (P.I. , J.M. Pezzuto), CA5

References

1. Cragg, G.M.; Newman, D. J.; Snader, K. M. J. Nat. Prod. 1997, 60, 52-60

2. Kinghorn, A. D.; Balandrin, M. F.; Eds. Human Medicinal Agents from Plants; ACS Symp. Ser. No. 534, American Chemical Society, Washington DC, 1993

3. Gullo, V. R.; Ed. The Discovery of Natural Produtcs with Therapeutic Potential; Butterworth-Heineman; Boston, 1994

4. Kinghorn, A. D.; Farnsworth, N. R.; Beecher, C. W. W. ; Soejarto, D. D.; Cordell, G. A.; Pezzuto, J. M.; Wani, M. C.; Brown. D. M.; O'Neill, M. J.; Lewis, J. A.; Besterman, J. M.; Int. J. Pharmacog. (Supp.) 1995, 33, 48-58

5. Pezzuto, J.M.; In Recent Advances in Phytochemistry, Vol. 29, Phytochemistry of Medicinal Plants (Arnason, J.T.; Mata, R.; Romeo, J. T.; Eds.); Plenum:New York, 1995; pp 19-45

6. Kinghorn, A. D.; Kennely, E. J. ; J. Chem. Educ. 1995, 72, 676-680

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